Ammonia Compressors Refrigeration Plant

INTRODUCTION

1 This circular gives advice on the precautions to be taken against the toxic, fire and explosion hazards presented by refrigeration systems containing ammonia. These are most likely to be found by LA enforcement officers at cold stores and food distribution warehouses. It applies to the entire system not simply the compressor house. It provides interim advice on matters of concern to enforcement officers pending revision of BS 4434:1980.

2 Appendix 1 outlines the general principles of refrigeration, Appendix 2 gives information on the results of the programme of special visits carried out in 1983 by Factory Inspectorate (F1) to examine present standards in the food industry and Appendix 3 gives detailed guidance on electrical standards. Enforcement officers should not overemphasise the hazards of ammonia compared with other refrigerants.

HAZARDS

Toxicity

3 Ammonia is a chemically reactive gas that is very soluble in water and is much lighter than air (vapour density 0.59 of that of air). Cold vapour (e.g. from leaks) may however be denser than air. Although there have been incidents of exposure to harmful concentrations of ammonia in the UK there have been few fatal accidents. Ammonia is characterised by a typical pungent odour and is detectable by most people at levels of about 50 ppm in the atmosphere. Although workers become tolerant to this effect and in the past have been able to work without distress at levels up to 70 ppm, currently the recommended exposure limit for ammonia is 25 ppm, 8 hour TWA (0.0025%) and the short term exposure limit is 35 ppm, 10 minute TWA. At 400 ppm, most people experience immediate nose and throat irritation, but suffer no permanent ill-effects after 30-60 minute exposure. A level of 700 ppm causes immediate irritation to the eyes, and a level of 1,700 ppm (0.17%) will give rise to repeated coughing and can be fatal after about 30 minutes exposure.

Exposure to concentrations exceeding 5,000 ppm (0.5%) for quite short periods can result in death. Response to the effects of ammonia varies widely between individuals, and the dose-response effects described above are likely to be those experienced by the more susceptible members of the population.

Fire and explosion

4 Ammonia forms a flammable mixture with air at concentrations between 16 and 25% v/v. There have however been very few incentive explosions involving ammonia compressor houses in the UK and all of the reported incidents involved ammonia leakage from plant under maintenance.

Existing guidance

5 Current guidance on the precautions which should be taken with ammonia refrigeration plant may be found in: British Standard 4434: 1980 "Requirements for Refrigeration Safety: Part 1, General". The requirements (particularly from the f ire and explosion standpoint) are similar to those in the earlier (1 969) version. However a' full revision of BS 4434 is taking place.

Precautions

6 Under normal circumstances people will not be able to bear ammonia concentrations at even a fraction of the flammable limit. The appropriate precautions are mainly those applicable against toxic effects in occupied areas and to work where sudden exposures are foreseeable, such as maintenance and repair work, including in particular filling and oil draining. Precautions against fire and explosion will be appropriate however, in unoccupied areas such as compressor houses and unattended plant such as cold stores where accumulations of vapour may go unnoticed.

PRECAUTIONS AGAINST TOXIC RISK

Respiratory protective equipment

7 Any person entering an area in which ammonia vapour is likely to be present at a significant level (eg for rescue or fault-finding purposes) must wear self-contained or airline breathing apparatus. This does not include routine visits to plant rooms etc. A suitable and properly maintained set should be conveniently sited close to, but outside, any area in which high levels of .ammonia vapour might arise. In no circumstances should anyone enter an area where a flammable concentration of gas may be present. Details of suitable apparatus are contained in Form 2501 "Certificate of Approval (Breathing Apparatus)," published annually by HSE. See also Guidance Note GS 5 regarding entry into confined spaces.

8 Suitable respiratory protective equipment must be worn by every person carrying out engineering maintenance work on any system where there is a risk of release of ammonia. Full face canister respirators with type A (blue) canisters give good protection in atmospheres up to 2% concentration or 20,000 ppm, for one hour. Work in such a concentration is likely to lead to discomfort quickly due to skin irritation as ammonia dissolves in perspiration. A list of suitable equipment is given in form 2502 "Certificate of Approval (Canister Gas Respirators)". For substantial jobs impervious suits may be necessary if the gas cannot be cleared.

9 Everyone who is likely to need to use respiratory protective equipment must be properly trained in its use and must be fully aware of its limitations. The equipment must be maintained, kept clean and examined at least once a month. Appropriate records should be kept. If canister respirators are used there must be an effective system for deciding when the canisters should be renewed.

Evacuation and emergency procedures

10 lt is essential that a clear emergency procedure is drawn up which details the precise duties of all staff and the arrangements for evacuation, rescue, first aid, plant isolation etc. It is particularly important that evacuation procedures are clearly set out and regularly practised where refrigeration systems are in working areas. A common method which may be suitable is to use the fire alarm provided that actuating points are immediately available at working areas. Personnel should be warned not to approach any vapour clouds. (Clouds may often look like steam because of the cooling of the released gas).

11 Adequate exits should be maintained from plant rooms at, all times. Personnel seriously affected by an ammonia escape suffer streaming eyes and violent coughing and rapidly become disorientated. They therefore require clear prior knowledge of a safe exit route.

Training in plant operation and maintenance

12 All personnel involved in the operation and maintenance of the plant must be adequately trained. The training should cover not only general principles of refrigeration but also specific points related to the particular plant. This applies as much to maintenance contractors as to an employer's own staff.

PLANT LOCATION

Plant not designed for outdoor location

13 In the case of standard refrigeration plant (ie plant not specifically designed for outdoor location) exposure to excessively low air temperatures may cause liquefaction of ammonia within the compressor leading to compressor damage, which could be hazardous. This type of plant should therefore be sited in a compressor house using the precautions described in BS 4434:1980 and outlined below. Compressor-houses should, where reasonably practicable, be fitted with explosion relief (eg by using lightweight fragile roof). Where loosely held panels are used as explosion relief, they should be suitably restrained (eg by chains) to prevent them becoming dangerous missiles in the event of an explosion.

14 ln order to facilitate the provision of ventilation and explosion relief, compressor-houses should incorporate at least one external wall. The siting of compressors in confined areas, basements, etc should be avoided wherever practicable. Doors between plant rooms or compressor-houses and other parts of the building should be self-closing and well-fitting.

Plant designed for outdoor location

15 Only plant specifically designed for the conditions should be installed outdoors. Such installations should be sited in a safe position in the open air with, if necessary, weather protection using a Dutch barn type structure which has an evenly distributed minimum open area equivalent to at least 50% of the total wall area.

Plant in workrooms

16 As a general principle the amount of plant containing ammonia situated in workrooms and other populated areas should be minimised. Ancillary plant such as surge drums and liquid pumps should wherever possible be sited away from working areas. Compressors are often noisy and this is another reason for not having them in working areas.

Ventilation

17 Compress or houses should be provided with adequate and suitable ventilation to meet the following requirements:

(1) Normal Ventilation Sufficient permanent ventilation should be provided to prevent build up of toxic concentrations of ammonia from operational leakage (eg from seals, glands etc). It is probable that the redrafted British Standard will insist on mechanical car ventilation rather than rely on rather uncertain natural ventilation.

(2) Emergency ventilation Provision should be made for sufficient mechanical ventilation to prevent flammable ammonia/air mixtures accumulating in the event of reasonably foreseeable plant or operational failure (eg valve failure). In such circumstances the aim should be to keep concentrations below 25% of the lower explosive limit (ie 4%).

18 The ventilation requirements for a particular installation will depend on the type, capacity, operating conditions and location of the plant and may require individual assessment by a ventilation engineer with appropriate expertise. However, the following general points apply:

(1) permanent natural or mechanical ventilation, or a combination of both, may be used for normal or emergency ventilation. Mechanical ventilation initiated by gas detectors or manually (in the case of continuously manned plants) may also be used for emergency ventilation (see para 26); and Appendix 3 for electrical safety of the system;

(2) the ventilation should discharge to a safe place in the open air;

(3) in considering the ventilation to be provided, the potential effects of cold on plant should be taken into account (see para 12);

(4) flow of air through cracks around windows, doors etc, or the opening of windows or doors should not be relied on for ventilation;

(5) the formulae in BS4434 for quantifying ventilation requirements are rules of thumb based on unstated assumptions (eg they take no account of room size or leak rates). Inspectors should advise that the formulae may be used as a basic guide but discretion in their detailed application to a particular plant should be stressed. This is particularly important with very large systems when the ventilation required by the formulae becomes impracticable; and

(6) it should be noted that the standard of ventilation given by the formulae in BS 4434: 1980 is not intended to deal with prolonged releases from major plant failure. However, the latter is very unlikely to occur in properly designed, constructed and maintained plant. Control of sources of ignition and plant shutdown (see paras 22-26) should also provide protection in such circumstances. Manually operated controls for emergency ventilation should be located in a safe, easily accessible place along with the control or switch for turning off the compressor.

Plant integrity

19 There can be serious corrosion of the low pressure. parts of pipework and plant due to condensation. It can progress unnoticed under lagging which is not effectively vapour sealed and is particularly rapid on plants which run intermittently and pass-through OoC. The general principles relating to the safety of pressure systems are appropriate. The system should be thoroughly examined by a competent person at regular intervals in accordance with a written scheme. There should be an effective maintenance scheme.

Pipework

20 All parts of refrigerating systems and in particular pipework should be positioned or protected to minimise the risk of impact damage, for example by fork lift trucks. Pipework and valves should be clearly marked to indicate their contents and function.

Oil drain system

21 Many of the reported incidents involving ammonia refrigeration systems have been the result of a malfunction of the oil drain system (designed to catch the "carry-over" of oil from the compressors). In most cases oil is drained from below liquid ammonia and is saturated with it. In addition the oil is viscous because it is cold. In order to minimise the risk of escape from this cause the following measures should be advised:

(1) where short distances are involved and adequate observation of the drain is possible oil drain pipes should terminate in a safe location in the open air. Valves on any pipe extension should not introduce the possibility of liquid ammonia being trapped; a bleed valve or hydrostatic relief valve venting to a safe place should be provided in the sections between valves, as appropriate;

(2) a double valve arrangement should be provided at oil drains. In addition to the operational manual valve, there should be an automatic closing spring or weight-loaded valve; and

(3) The use of oil drain catchpots. These are a useful feature on new plant, but existing plant cannot normally be easily modified. Before the oil is drained, the catchpot is isolated from the liquid ammonia/oil feedline and the catchpot is electrically heated to boil off any ammonia which flows as a vapour to the low pressure side of the system. When the catchpot is warm, it is also isolated on the vapour side and the oil is then drained from it.

Ammonia filling point

22 Ammonia filling points should be located in safe, well ventilated positions and, where reasonably practicable, in the open air. Filling points should be sited away from sources of ignition.

PRECAUTIONS AGAINST FIRE AND EXPLOSION RISK

Sources of ignition

23 All likely sources of ignition (naked flames etc) should be eliminated from compressor houses and from the immediate vicinity of externally located plant.

Electrical equipment

24 Guidance on electrical apparatus for use in potentially explosive atmospheres is given in RS 5345: Part 1: 1976 "Code of Practice for the Selection, Installation and Maintenance of Electrical Apparatus for Use in Potentially Explosive Atmospheres, Part 1, Basic Requirements for all Parts of the Code"; BS 4434: 1980, Clause 13 "Electrical Installations". The approaches followed by the above documents differ.

25 As a general principle, electrical equipment should be sited outside the compressor room in a safe location. However, when it is necessarily sited in the room, it should be in accordance with the guidance given in para 27.

26 Where the ammonia compressors and refrigeration plant are located in the same room as the supply switch gear for the-premises relocation would probably be inconvenient and costly. In such cases, Field Consultant Group (FCG) advise on the most suitable safety precautions in the particular case should be sought.

Electrical apparatus selection criteria

27 The use of electrical apparatus in refrigeration plants using ammonia has been considered a special case because of the flammability characteristics of the gas (high LEL and narrow explosive range) and the fact that it can be detected at very low levels by smell. This has resulted in a number of options which may be considered when selecting electrical apparatus for ammonia plants and these are considered in Appendix 3.

OTHER RISKS

28 Refrigeration systems often have associated risks which may require attention, These include the risk of trapping in cold stores and chills, the handling of very cold products and microbiological problems associated with cooling towers used for the condenser.

ENFORCEMENT APPROACH
29 Enforcement officers should advise that ammonia refrigeration plant should comply with the guidance in BS 4434: 1980 as amended and augmented by the information in this circular. They should however bear in mind:

(1) ammonia presents a toxic risk at concentrations far below those at which it presents any fire or explosion risk. There have been 2 gassing fatalities between 1977 and 1983 in the UK but only 3 incentive ammonia/air explosions in the last 20 years;

(2) the potential consequences of an incident in terms of injury to personnel, and the general public should be assessed;

(3) BS4434 was first published in 1969 and was not intended to be retrospective, although improvements in installations which pre-date the standard should be recommended, where reasonably practicable;

(4) analysis of the l983 visits strongly suggest that where poor conditions of the plant are found there is often inadequate attention to evacuation and emergency action; and

(5) where enforcement officers encounter maintenance contractors they should make enquiries about their working practices and training.
Further advice

30 This is a complicated technical subject and there are strong trade pressure groups. Enforcement officers are recommended to seek the advice of HSEs Field Consultant Group (FCG) via the Local Enforcement Liaison Officer (ELO), before considering enforcement action.
________________________________________
Ammonia is used as a refrigerant because of particular thermodynamic properties which enable it to move heat far more efficiently than other refrigerant gases such as halogenated hydrocarbons. It is particularly suited to working in the range approximately OoC to -30oC and hence is widely used for food preservation, the chilling of liquids such as milk, beer and soft drinks, and in the chemical industry. New systems continue to be installed.

2. A simple system theoretically needs 4 components:

(1) evaporator;

(2) compressor;

(3) condenser; and
(4) reducing valve

In practice other components such as oil separator, intercooler, liquid receiver, surge drum and liquid pumps are often found.

3 The useful refrigeration is produced at the evaporator. Liquid ammonia at low pressure, and hence low temperature, takes in heat by vaporising. This vapour is removed by the compressor which, in compressing it, raises the temperature from below to above ambient. The hot compressed gas gives up the heat by condensing to a liquid in the condenser. The high pressure liquid then passes through the pressure reducing valve to the evaporator. At the valve the liquid is cooled as some vapour flashes off. The remaining liquid is available for use in the evaporator.

4 In a practical system it is likely there will be other items of plant. An oil separator removes suspended oil carried over from the compressor and either returns it to the (pressurised) crank-case or holds it for draining in some way. There may be a multi-stage compressor with an intercooler. This is cooled by bleeding high pressure liquid into the low pressure side.

Downstream of the condenser is generally a liqui